Publication:
Facile oxidative hydrolysis of acetals to esters using hypervalent iodine(III)/LiBr combination in water

Issued Date

2010-04-03

Resource Type

Article

ISSN

00404020

DOI

10.1016/j.tet.2010.01.098

Other identifier(s)

2-s2.0-77649182466

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Tetrahedron. Vol.66, No.14 (2010), 2732-2735

Suggested Citation

Waraporn Panchan, Supanimit Chiampanichayakul, Deanna L. Snyder, Siriporn Yodbuntung, Manat Pohmakotr, Vichai Reutrakul, Thaworn Jaipetch, Chutima Kuhakarn Facile oxidative hydrolysis of acetals to esters using hypervalent iodine(III)/LiBr combination in water. Tetrahedron. Vol.66, No.14 (2010), 2732-2735. doi:10.1016/j.tet.2010.01.098 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/28738

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Title

Facile oxidative hydrolysis of acetals to esters using hypervalent iodine(III)/LiBr combination in water

Author(s)

Waraporn Panchan
 Supanimit Chiampanichayakul
 Deanna L. Snyder
 Siriporn Yodbuntung
 Manat Pohmakotr
 Vichai Reutrakul
 Thaworn Jaipetch
 Chutima Kuhakarn

Other Contributor(s)

Mahidol University

Abstract

The combination of (diacetoxy)iodobenzene (PhI(OAc)2, DIB) and lithium bromide (LiBr) efficiently oxidized cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters in good to excellent yields. The merits of this reaction are that it employs commercially available and non-explosive hypervalent iodine(III) reagent, water as the solvent, a short reaction time, and mild reaction conditions. © 2010 Elsevier Ltd. All rights reserved.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Pharmacology, Toxicology and Pharmaceutics

Availability

URI

https://repository.li.mahidol.ac.th/handle/123456789/28738

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Scopus 2006-2010