Publication:
IBX/n-Bu<inf>4</inf>NBr/CH<inf>2</inf>Cl<inf>2</inf>-H<inf>2</inf>O: A new mild system for selective oxidation of secondary alcohols

Issued Date

2005-09-19

Resource Type

Article

ISSN

00404020

DOI

10.1016/j.tet.2005.07.051

Other identifier(s)

2-s2.0-23944511343

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Tetrahedron. Vol.61, No.38 (2005), 8995-9000

Suggested Citation

Chutima Kuhakarn, Krisada Kittigowittana, Manat Pohmakotr, Vichai Reutrakul IBX/n-Bu<inf>4</inf>NBr/CH<inf>2</inf>Cl<inf>2</inf>-H<inf>2</inf>O: A new mild system for selective oxidation of secondary alcohols. Tetrahedron. Vol.61, No.38 (2005), 8995-9000. doi:10.1016/j.tet.2005.07.051 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/16295

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Title

IBX/n-Bu<inf>4</inf>NBr/CH<inf>2</inf>Cl<inf>2</inf>-H<inf>2</inf>O: A new mild system for selective oxidation of secondary alcohols

Author(s)

Chutima Kuhakarn
 Krisada Kittigowittana
 Manat Pohmakotr
 Vichai Reutrakul

Other Contributor(s)

Mahidol University

Abstract

A new alternative system for the chemoselective oxidation of secondary hydroxyl group to ketone with IBX/n-Bu4NBr in CH2Cl2-H2O has been developed. Under the reaction conditions, the secondary hydroxyl group was highly chemoselectively oxidized to the corresponding ketone, in moderate to good yields at rt, in the presence of primary hydroxyl group within the same molecule. © 2005 Elsevier Ltd. All rights reserved.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Pharmacology, Toxicology and Pharmaceutics

Availability

URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/16295

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Scopus 2001-2005