Publication: Effect of LCP and rPET as reinforcing materials on rheology, morphology, and thermal properties of in situ microfibrillar-reinforced elastomer composites
Issued Date
2009-05-15
Resource Type
ISSN
10974628
00218995
00218995
Other identifier(s)
2-s2.0-64249086023
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Mahidol University
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SCOPUS
Bibliographic Citation
Journal of Applied Polymer Science. Vol.112, No.4 (2009), 1897-1908
Suggested Citation
Sunan Saikrasun, Panpirada Limpisawasdi, Taweechai Amornsakchai Effect of LCP and rPET as reinforcing materials on rheology, morphology, and thermal properties of in situ microfibrillar-reinforced elastomer composites. Journal of Applied Polymer Science. Vol.112, No.4 (2009), 1897-1908. doi:10.1002/app.29715 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/27420
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Title
Effect of LCP and rPET as reinforcing materials on rheology, morphology, and thermal properties of in situ microfibrillar-reinforced elastomer composites
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Abstract
Microfibrillar-reinforced elastomer composites based on two dispersed phases, liquid crystalline polymer (LCP) and recycled poly(ethylene terephthalate)(rPET), and styrene-(ethylene butyiene)-styrene (SEBS) were prepared using extrusion process. The Theological behavior, morphology, and thermal stability of SEBS/LCP and SEBS/ rPET blends containing various dispersed phase contents were investigated. All blends and LCP exhibited shear thinning behavior, whereas Newtonian fluid behavior was observed for rPET. The incorporation of both LCP and rPET into SEBS significantly improved the processability by bringing down the melt viscosity of the blend system. The fibrillation of LCP dispersed phase was clearly observed in asextruded strand with addition of LCP up to 20-30 wt %. Although the viscosity ratio of SEBS/rPET system is very low (0.03), rPET domains mostly appeared as droplets in as-extruded strand. The results obtained from thermogravimetric analysis suggested that an addition of LCP and rPET into the elastomer matrix improved the thermal resistance significantly in air but not in nitrogen. The simultaneous DSC profiles revealed that the thermal degradation of all polymers examined were endothermic and exothermic in nitrogen and in air, respectively. © 2009 Wiley Periodicals, Inc.