Publication:
Nucleophilic trifluoromethylation of anhydrides employing (trifluoromethyl)trimethylsilane: Synthesis of γ-trifluoromethylated γ-butyrolactones

Issued Date

2013-01-01

Resource Type

Article

ISSN

00221139

DOI

10.1016/j.jfluchem.2013.06.006

Other identifier(s)

2-s2.0-84885928593

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Journal of Fluorine Chemistry. Vol.154, (2013), 37-42

Suggested Citation

Chonticha Masusai, Darunee Soorukram, Chutima Kuhakarn, Patoomratana Tuchinda, Vichai Reutrakul, Manat Pohmakotr Nucleophilic trifluoromethylation of anhydrides employing (trifluoromethyl)trimethylsilane: Synthesis of γ-trifluoromethylated γ-butyrolactones. Journal of Fluorine Chemistry. Vol.154, (2013), 37-42. doi:10.1016/j.jfluchem.2013.06.006 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/31389

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Title

Nucleophilic trifluoromethylation of anhydrides employing (trifluoromethyl)trimethylsilane: Synthesis of γ-trifluoromethylated γ-butyrolactones

Author(s)

Chonticha Masusai
 Darunee Soorukram
 Chutima Kuhakarn
 Patoomratana Tuchinda
 Vichai Reutrakul
 Manat Pohmakotr

Other Contributor(s)

Mahidol University

Abstract

Fluoride-catalyzed nucleophilic trifluoromethylation of acid anhydrides using CF3SiMe3 provided the corresponding γ-hydroxy-γ- trifluoromethyl-γ-butyrolactones. The utility of these adducts was further demonstrated by treatment with Grignard reagents, leading to γ-trifluoromethylated γ-butyrolactones. © 2013 Elsevier B.V. All rights reserved.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Environmental Science

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URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/31389

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