Publication: Chelating agent- and surfactant-assisted synthesis of manganese oxide/carbon nanotube composite for electrochemical capacitors
Issued Date
2013-03-01
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00255408
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2-s2.0-84872851967
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Mahidol University
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SCOPUS
Bibliographic Citation
Materials Research Bulletin. Vol.48, No.3 (2013), 1204-1212
Suggested Citation
Jedsada Sodtipinta, Weeraphat Pon-On, Waret Veerasai, Siwaporn Meejoo Smith, Pasit Pakawatpanurut Chelating agent- and surfactant-assisted synthesis of manganese oxide/carbon nanotube composite for electrochemical capacitors. Materials Research Bulletin. Vol.48, No.3 (2013), 1204-1212. doi:10.1016/j.materresbull.2012.12.042 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/31763
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Title
Chelating agent- and surfactant-assisted synthesis of manganese oxide/carbon nanotube composite for electrochemical capacitors
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Abstract
Different morphologies of manganese oxide/carbon nanotube (MnO2/CNT) composites were prepared using ethylenediaminetetraacetic acid (EDTA) or sodium dodecyl sulfate (SDS) as soft templates. Using EDTA, the resulting composite showed hierarchical structure, while an assembly of rod-like structures was obtained when SDS was used. The surface of CNT in the composites was covered with a layer of manganese oxide of 2-3 nm in thickness. The surface area was higher when EDTA was used in the synthesis (246 m2/g for EDTA route compared with 227 m2/g for SDS route), as is also the case for the specific capacitance (154 F/g based on cyclic voltammetry and 115 F/g based on galvanostatic charge/discharge for 95% MnO2loading of EDTA route compared with 80.3 F/g based on cyclic voltammetry and 79.2 F/g based on galvanostatic charge/discharge for 80% MnO2loading of SDS route). Overall, the MnO2/CNT composites showed good charge/discharge reversibility. Given these favorable properties along with the simplicity of the preparation, the MnO2/CNT/Ni-foam electrode can potentially be used in future large-scale development of the electrochemical capacitors. © 2012 Elsevier Ltd. All rights reserved.