Publication:
Structural characterization of highly cis-1,4-polybutadiene: A comparing study in swollen and solid state using NMR technique

1

Issued Date

2001-08-31

Resource Type

Article

ISSN

01700839

DOI

10.1007/s002890170035

Other identifier(s)

2-s2.0-0034886830

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Polymer Bulletin. Vol.46, No.6 (2001), 479-485

Suggested Citation

Jitladda Sakdapipanich, Tippawan Kowitteerawut, Kawahara Seiichi, Yasuyuki Tanaka Structural characterization of highly cis-1,4-polybutadiene: A comparing study in swollen and solid state using NMR technique. Polymer Bulletin. Vol.46, No.6 (2001), 479-485. doi:10.1007/s002890170035 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/26504

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Title

Structural characterization of highly cis-1,4-polybutadiene: A comparing study in swollen and solid state using NMR technique

Author(s)

Jitladda Sakdapipanich
 Tippawan Kowitteerawut
 Kawahara Seiichi
 Yasuyuki Tanaka

Other Contributor(s)

Mahidol University
 Nagaoka University of Technology

Abstract

Commercial highly cis-1,4-polybutadiene was cured out by benzoyl peroxide from 3 to 12 phr in toluene solution. The structural characterization of resulting gel fraction or cured rubber was carried out in both swollen- and solid-state 13C-NMR measurements. The assignment of observed chemical shift proposed by using a shift factor method and empirical calculation using HOSE method.

Keyword(s)

Chemistry
 Materials Science
 Physics and Astronomy

Availability

URI

https://repository.li.mahidol.ac.th/handle/123456789/26504

Collections

Scopus 2001-2005