Publication: Temperature-dependent schlieren effect in liquid flow for chemical analysis
Issued Date
2018-10-01
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ISSN
00399140
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2-s2.0-85047274682
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Mahidol University
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SCOPUS
Bibliographic Citation
Talanta. Vol.188, (2018), 74-80
Suggested Citation
Jintana Suwanrut, Nattapong Chantipmanee, Wichayaporn Kamsong, Supatana Buking, Thitirat Mantim, Phoonthawee Saetear, Duangjai Nacapricha Temperature-dependent schlieren effect in liquid flow for chemical analysis. Talanta. Vol.188, (2018), 74-80. doi:10.1016/j.talanta.2018.05.055 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/45474
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Title
Temperature-dependent schlieren effect in liquid flow for chemical analysis
Abstract
© 2018 Elsevier B.V. In flow analysis, such as flow injection analysis, liquid lens is formed at the boundary between two adjacent liquid media which have different refractive indices. Light refraction at the liquid interface gives the so-called 'schlieren signal’. Schlieren effect is both concentration-dependent and temperature-dependent. In this work, the schlieren signal from temperature difference was quantitatively investigated for application in enthalpimetric measurement. The schlieren phenomena was then exploited for chemical analysis. A thermal insulated single flow line manifold was constructed using deionized water at 23 °C as the carrier. Deionized water at various temperatures in the range of 5–85 °C was injected into the carrier flow. A correlation between the schlieren signal and sample temperature was observed. A heat exchanger unit (HEU), consisting of a small volume glass-reaction chamber with a surrounding water jacket, was constructed. The unit was thermally insulated in a double layer cylindrical PVC unit. For demonstrating the applicability of temperature-dependent schlieren effect in chemical analysis, the exothermic oxidation reaction between acid dichromate and ethanol or ascorbic acid was employed with heat transferring to the surrounding water layer. When an aliquot of water from the HEU is injected into the constant temperature flow line the observed schlieren signal was dependent on the analyte concentration. Linear calibration (r2 > 0.99) were obtained covering the concentration range of ethanol and ascorbic acid as found in samples. The developed flow system provides good precision (RSD < 5%) with sample throughput of 4 sample h−1. The system were applied to the determination of ethanol in Thai white spirit and ascorbic acid in vitamin C tablets, respectively. The quantitative results obtained from the schlieren method were in agreement with the comparative methods.