Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation
Issued Date
2023-03-17
Resource Type
ISSN
13597345
eISSN
1364548X
Scopus ID
2-s2.0-85152173915
Pubmed ID
36942515
Journal Title
Chemical Communications
Volume
59
Issue
28
Start Page
4193
End Page
4196
Rights Holder(s)
SCOPUS
Bibliographic Citation
Chemical Communications Vol.59 No.28 (2023) , 4193-4196
Suggested Citation
Manguin R., Galiana-Cameo M., Kittikool T., Barthes C., Thongpaen J., Bancal E., Mallet-Ladeira S., Yotphan S., Castarlenas R., Mauduit M., Sortais J.B., Baslé O. Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation. Chemical Communications Vol.59 No.28 (2023) , 4193-4196. 4196. doi:10.1039/d2cc06865f Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/81704
Title
Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation
Other Contributor(s)
Abstract
A series of (NHC)(cod)Ir(i) complexes bearing NHC-carboxylate ligands were efficiently synthesized and fully characterized. Their solid-state structures confirmed the bidentate coordination mode of these LX-type NHC ligands. These unprecedented iridium(i) complexes demonstrated efficient catalytic activities in dehydrogenative directed C-H silylation of arenes, and allowed for excellent ortho-selectivity control with aromatic silylating agents.